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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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(-)-Asparagine → Aspartate asparagine

HRID 736016
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HRID 736016 반응식
[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([O-:6])=[O:5].[NH4+].[NH4+].[NH2:12][C@H:13]([C:18]([OH:20])=[O:19])[CH2:14][C:15](=[O:17])[NH2:16].[OH-].[NH4+]>O>[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([O-:6])=[O:5].[NH2:12][C@H:13]([C:18]([OH:20])=[O:19])[CH2:14][C:15](=[O:17])[NH2:16]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

5

반응물 3

HCID 6267(-)-AsparagineHCID 14923Ammonium Hydroxide3회HCID 86590683Ammonium Aspartate

생성물 1

HCID 86612007Aspartate asparagine

시약·촉매·용매 1

HCID 962Water용매2회

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온도
3 °C

실험 절차

The reaction conditions and procedures of Example 9, for production of copolymers of ammonium aspartate and asparagine from polysuccinimides, were followed with the additional inclusion of crosslinker molecules along with the ammonium hydroxide. Accordingly, a sample of polysuccinimide, preferably comprised of high Mw, linear molecules (e.g. from Example 3), was slurried in water at 20 g in 100 ml water. The slurry was cooled to 2-4° C., by use of a refrigerated recirculating bath and a water-jacketed glass vessel, and precooled, concentrated ammonium hydroxide (twofold excess) was added, keeping the temperature at 2-4° C. The crosslinker, in a cooled solution of ammonium hydroxide, was added to the precooled slurry of polysuccinimide, and the reaction mixture was then stirred for 2 to 4 hours until a complete solution was formed. Water was removed at 80° C. in a forced-air oven, producing a dried product of lightly crosslinked aspartate/asparagine copolymer.

후처리

  1. customThe reaction conditions and procedures of Example 9
  2. customat 2-4° C
  3. customwas formed
  4. customWater was removed at 80° C. in a forced-air oven

출처 및 근거

ORD 기록
ord-95e7b14ed6c9480a81cd61741e70ec06
출처 데이터셋
uspto-grants-2009_09
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US07595002B2

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