1,3-Dichloro-4,6-dinitrobenzene → 4,6-Dichlorobenzene-1,3-diamine

HRID 74023

반응식

HRID 74023 반응식
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([N+:9]([O-])=O)=[CH:4][C:3]=1[N+:12]([O-])=O>CC#N>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([NH2:9])=[CH:4][C:3]=1[NH2:12]

참가 물질

3

반응물 1

HCID 772861,3-Dichloro-4,6-dinitrobenzene

생성물 1

HCID 33728694,6-Dichlorobenzene-1,3-diamine

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

4,6-Dichloro-benzene-1,3-diamine (D-2) was synthesized following the general scheme above starting from 1,5-dichloro-2,4-dinitro-benzene. Yield (95%). HPLC ret. time 1.88 min, 10-99% CH3CN, 5 min run; ESI-MS 177.1 m/z (MH+).

후처리

  1. customYield (95%)

출처 및 근거

ORD 기록
ord-615690da0b644d88ab2646ee0b7e840f
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08829204B2

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