HCID 21468914, 화합물 → HCID 21468845, 화합물

HRID 743864노트

반응식

HRID 743864 반응식
[C:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:15]=[CH:14][C:12]([NH2:13])=[C:11]([N+:16]([O-])=O)[CH:10]=1)#[N:2]>C(O)C.[Pd]>[NH2:16][C:11]1[CH:10]=[C:9]([C:4]2[CH:5]=[CH:6][CH:7]=[CH:8][C:3]=2[C:1]#[N:2])[CH:15]=[CH:14][C:12]=1[NH2:13]

참가 물질

4

반응물 1

HCID 21468914HCID 21468914, 화합물

생성물 1

HCID 21468845HCID 21468845, 화합물

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

4-(2-Cyanophenyl)-2-nitroaniline (0.042 moles,10 g.) was dissolved in 200 ml ethanol and hydrogenated at 40 psi over 10 g of 10% Pd/C. The solution was filtered, concentrated, and purified by HPLC eluted with a gradient of 0-50% ethyl acetate in toluene. (MS)

후처리

  1. filtrationThe solution was filtered
  2. concentrationconcentrated
  3. custompurified by HPLC
  4. washeluted with a gradient of 0-50% ethyl acetate in toluene

출처 및 근거

ORD 기록
ord-fa9582c4eb114fb683ee9609129e730a
출처 데이터셋
uspto-grants-1996_09
특허 번호
US05556981

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