3-Bromothiophene → Stannane, tributyl-3-thienyl-

HRID 744986노트

반응식

HRID 744986 반응식
[CH2:1]([Sn:5]([CH2:15][CH2:16][CH2:17][CH3:18])([CH2:11][CH2:12][CH2:13][CH3:14])[C:6]1[CH:10]=[CH:9]O[CH:7]=1)[CH2:2][CH2:3][CH3:4].BrC1C=C[S:22]C=1>>[CH2:1]([Sn:5]([CH2:15][CH2:16][CH2:17][CH3:18])([CH2:11][CH2:12][CH2:13][CH3:14])[C:6]1[CH:10]=[CH:9][S:22][CH:7]=1)[CH2:2][CH2:3][CH3:4]

참가 물질

3

반응물 2

HCID 133833-BromothiopheneHCID 11760097Stannane, tributyl-3-furanyl-

생성물 1

HCID 10959689Stannane, tributyl-3-thienyl-

실험 절차

Using the method for the preparation of 3-tributylstannylfuran, 2.50 g (15.39 mmoles) of 3-bromothiophene gave 1.31 g (Y: 23%) of the title product. 1H NMR (CDCl3): δ7.46 (m, 1H), 7.34 (d, J=2.3 Hz, 1H), 7.16 (d, J=4.6 Hz, 1H), 1.52 (m, 6H), 0.132 (m, 6H), 1.05 (t, J=8.2 Hz, 6H), 0.89 (t, J=7.2 Hz, 9H). MS (DCI)m/e: 375 (MH+).

출처 및 근거

ORD 기록
ord-3ec96a505a544b2c9364654ec26281f8
출처 데이터셋
uspto-grants-1996_09
특허 번호
US05559248

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