Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethanol → Sodium 10-bromodecane sulfonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethanol | HCID 702 | — |
| 반응물 | Sodium Sulfite | HCID 24437 | — |
| 반응물 | 1,10-Dibromodecane | HCID 221483 | — |
| 반응물 | 2-Bromoethanesulfonic acid, sodium salt | HCID 23666797 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Sodium 10-bromodecane sulfonate | HCID 23667836 | — |
반응 단계
1,10-Dibromodecane (7.5 g, 25 mmol), sodium sulfite (1.4 g, 11 mmol), ethanol (25 mL) and water (20 mL) were reacted and worked up analogously to sodium 2-bromoethane sulfonate. Yield: 1.8 g (23%) colorless solid, melting point 342° C., IR (ATR): {tilde over (ν)}=3541 (s), 3481 (s), 2916 (s), 2874 (m), 2853 (s), 2095 (w), 1627 (m), 1472 (m), 1307 (w), 1281 (w), 1250 (w), 1230 (m), 1197 (m), 1178 (s), 1055 (m), 1044 (m), 968 (w), 796 (m), 721 (w), 640 (w), 608 cm−1 (m). HRMS (ESI) (C10H21BrNaO3S+): calculated 323.0287. found 323.0602, Δ=31.5 mmu.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08835484B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-5c224bff05fe40cfb69e18587acd3747 |
| 출처 메모 | uspto-grants-2014_09 |