Ethanol → Sodium 10-bromodecane sulfonate

HRID 76121

반응식

HRID 76121 반응식
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]Br.[S:13]([O-:16])([O-:15])=[O:14].[Na+:17].[Na+].C(O)C.BrCCS([O-])(=O)=O.[Na+]>O>[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][S:13]([O-:16])(=[O:15])=[O:14].[Na+:17]

참가 물질

6

반응물 4

HCID 702EthanolHCID 24437Sodium SulfiteHCID 2214831,10-DibromodecaneHCID 236667972-Bromoethanesulfonic acid, sodium salt

생성물 1

HCID 23667836Sodium 10-bromodecane sulfonate

시약·촉매·용매 1

HCID 962Water용매

실험 절차

1,10-Dibromodecane (7.5 g, 25 mmol), sodium sulfite (1.4 g, 11 mmol), ethanol (25 mL) and water (20 mL) were reacted and worked up analogously to sodium 2-bromoethane sulfonate. Yield: 1.8 g (23%) colorless solid, melting point 342° C., IR (ATR): {tilde over (ν)}=3541 (s), 3481 (s), 2916 (s), 2874 (m), 2853 (s), 2095 (w), 1627 (m), 1472 (m), 1307 (w), 1281 (w), 1250 (w), 1230 (m), 1197 (m), 1178 (s), 1055 (m), 1044 (m), 968 (w), 796 (m), 721 (w), 640 (w), 608 cm−1 (m). HRMS (ESI) (C10H21BrNaO3S+): calculated 323.0287. found 323.0602, Δ=31.5 mmu.

출처 및 근거

ORD 기록
ord-5c224bff05fe40cfb69e18587acd3747
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08835484B2

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