참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Nitromethane | HCID 6375 | — |
| 반응물 | Benzaldehyde, 4-(phenylmethoxy)- | HCID 78109 | — |
| 반응물 | Ammonium Acetate | HCID 517165 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | (E)-1-(Benzyloxy)-4-(2-nitrovinyl)benzene | HCID 5702926 | 97.9% |
반응 단계
To a mixture of 4-benzyloxy benzaldehyde (50 g, 0.24 mol) and acetic acid (200 mL) were added nitromethane (64 mL, 1.2 mol) and ammonium acetate (36 g, 0.47 mol), which was stirred for 90 minutes at 100° C. The reaction mixture was cooled to room temperature, and water (1 L) was added at the same temperature. The deposited solids were filtered to obtain the title compound (60 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08841327B2 |
|---|
| 출처 데이터셋 | uspto-grants-2014_09 |
|---|
| ORD ID | ord-4245e0c393014aae9eda696d8b07c9f8 |
|---|
| 출처 메모 | uspto-grants-2014_09 |
|---|
