Dichloromethane → 5-(9H-fluoren-2-yl)-2,3,3a,4,6,6a-hexahydro-1H-pyrrolo[3,4-c]pyrrole

반응식

[C:1]([O:2][C:3](=[O:4])[N:8]1[CH2:9][CH:10]2[CH2:11][N:12]([c:16]3[cH:17][c:18]4[c:26]([cH:27][cH:28]3)-[c:25]3[c:20]([cH:21][cH:22][cH:23][cH:24]3)[CH2:19]4)[CH2:13][CH:14]2[CH2:15]1)([CH3:5])([CH3:6])[CH3:7].[Cl:36][CH2:37][Cl:38].[OH:29][C:30]([C:31]([F:32])([F:33])[F:34])=[O:35]>>[NH:8]1[CH2:9][CH:10]2[CH2:11][N:12]([c:16]3[cH:17][c:18]4[c:26]([cH:27][cH:28]3)-[c:25]3[c:20]([cH:21][cH:22][cH:23][cH:24]3)[CH2:19]4)[CH2:13][CH:14]2[CH2:15]1

참가 물질

반응물 3

HCID 6344Dichloromethane

HCID 6422Trifluoroacetic acid

HCID 671637455-(9H-Fluoren-2-yl)-hexahydropyrrolo[3,4-c]pyrrole-2-carboxylic acid tert-butyl ester

생성물 1

HCID 574398335-(9H-fluoren-2-yl)-2,3,3a,4,6,6a-hexahydro-1H-pyrrolo[3,4-c]pyrrole

출처 및 근거

ORD 기록: ord-3510e11ff0c348bcbb7bbce4d376b53b
출처 데이터셋: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

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