Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Benzyloxy-4-phenyl-butan-2-ol → 1-Benzyloxy-4-phenyl-butan-2-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Benzyloxy-4-phenyl-butan-2-ol | HCID 13347371 | — |
| 반응물 | HCID 178418287 | HCID 178418287 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 1-Benzyloxy-4-phenyl-butan-2-one | HCID 21992782 | 68.3% |
반응 단계
To a solution of 1-benzyloxy-4-phenyl-butan-2-ol, (8.4 g, 32.8 mmol) in dichloromethane (400 mL) is added a mixture of pyridinium chlorochromate (14.1 g, 65.6 mmol) with SiO2 (14 g) and stirred for 3 h at room temperature. The mixture is filtered through a pad of SiO2 and concentrated to provide the title compound 5.7 g (68%) as a colorless liquid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07087626B2 |
| 출처 데이터셋 | uspto-grants-2006_08 |
| ORD ID | ord-16f69d03a0444212bf99c7b0fcc0694b |
| 출처 메모 | uspto-grants-2006_08 |