Benzene → Cyclododecene, (E)-

HRID 839427

반응식

HRID 839427 반응식
[CH:1]1=[CH:2][CH2:3][CH2:4][CH:5]=[CH:6][CH2:7][CH2:8][CH2:9][CH2:10]1.[CH:11]1C=CC=C[CH:12]=1>[W](Cl)(Cl)(Cl)(Cl)(Cl)Cl>[CH:1]1[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:12][CH:11]=1

참가 물질

4

반응물 2

HCID 241BenzeneHCID 5365643(1E,5Z)-Cyclodecadiene

생성물 1

HCID 15164Cyclododecene, (E)-

시약·촉매·용매 1

HCID 83301Tungsten hexachloride촉매

실험 절차

Using the mode of operation set forth in Example 1--except for Experiment 31, wherein 15 ml. of monomer was employed--30 ml. (158 mmol.) of cyclododecene (mixture of isomers with 70.3% trans- and 29.7% cis-cyclododecene) was polymerized with a catalyst of varying amounts of cis,trans-1,5-cyclodecadiene and 1.5 ml. of a 0.1-molar solution of tungsten hexachloride in benzene. The results of Comparative Experiment B, as well as Experiments 31-38, are indicated in Table V.

후처리

  1. customThe results of Comparative Experiment B

출처 및 근거

ORD 기록
ord-504d1520085f48709c559bc4735de07c
출처 데이터셋
uspto-grants-1978_06
특허 번호
US04095033

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