참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Acetone | HCID 180 | — |
| 반응물 | Water | HCID 962 | — |
| 반응물 | Stearyl acrylate | HCID 62552 | — |
| 반응물 | Sodium Persulfate | HCID 62655 | — |
| 반응물 | alpha-Methylene butyrolactone | HCID 68352 | — |
| 반응물 | Sodium Stearate | HCID 2724691 | — |
| 생성물 | alpha-Methylene-gamma-Butyrolactone Octadecyl Acrylate | HCID 86664979 | — |
반응 단계
To a high-pressure reactor with a magnetic stirrer is charged 31.50 g (1.75 mol) water, 13.50 g (0.232 mol) acetone, 25.0 g (7.70×10−2 mol) octadecyl acrylate, 25.0 g (0.255 mol) α-methylene-γ-butyrolactone, 1.25 g (4.08×10−3 mol) sodium stearate, and 0.13 g (5.46×10−4 mol) sodium persulfate. Two freeze-pump-thaw cycles using liquid nitrogen sufficiently degass the reaction medium prior to sealing the reactor and heating to 60° C. The reaction is stirred for 16 hours at 60° C. before cooling to room temperature and drying under vacuum at elevated temperature for isolation.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08846817B2 |
|---|
| 출처 데이터셋 | uspto-grants-2014_09 |
|---|
| ORD ID | ord-0ab276d882e44ad1b14ab99621658f7b |
|---|
| 출처 메모 | uspto-grants-2014_09 |
|---|
