Benzene → alpha-Methylene-gamma-Valerolactone Divinyl Benzene

HRID 83957

반응식

HRID 83957 반응식
[CH2:1]=[C:2]1[CH2:7][CH:6]([CH3:8])[O:5][C:3]1=[O:4].C1C=CC=CC=1.[CH:15]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[CH:23]=[CH2:24])=[CH2:16]>>[CH2:1]=[C:2]1[CH2:7][CH:6]([CH3:8])[O:5][C:3]1=[O:4].[CH:15]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[CH:23]=[CH2:24])=[CH2:16]

참가 물질

4

반응물 3

HCID 241BenzeneHCID 666661,2-DiethenylbenzeneHCID 99939gamma-Methyl-alpha-methylene-gamma-butyrolactone

생성물 1

HCID 86664985alpha-Methylene-gamma-Valerolactone Divinyl Benzene

반응 조건

온도
65 °C

실험 절차

To a dry 100 mL round bottom flask equipped with a magnetic stir bar was charged 1.0153 g (8.98×10−3 mol) α-methylene-γ-valerolactone, 16.78 g (0.215 mol) benzene, 0.0561 g (4.31×10−4 mol) divinyl benzene, and 0.0067 g (4.08×10−5 mol) azobisisobutylnitrile. The reactor was purged with nitrogen for 30 minutes before heating to 65° C. The reactor was held at 65° C. for 5 hours before letting cooling the reaction mixture to room temperature and drying under vacuum.

후처리

  1. customTo a dry 100 mL round bottom flask equipped with a magnetic stir bar
  2. customThe reactor was purged with nitrogen for 30 minutes
  3. temperaturebefore letting cooling the reaction mixture to room temperature
  4. customdrying under vacuum

출처 및 근거

ORD 기록
ord-cc45147e8cd34e0daca082f656717305
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08846817B2

연결된 노트

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