Potassium Hydroxide → HCID 12474700, 화합물

HRID 840084노트

반응식

HRID 840084 반응식
[CH2:1]([C:9]1[CH:10]([C:12]([O:14]CC)=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH-].[K+]>CCOCC>[CH2:1]([C:9]1[CH:10]([C:12]([OH:14])=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

참가 물질

4

반응물 2

HCID 14797Potassium HydroxideHCID 22621698Ethyl 2-octylcycloprop-2-ene-1-carboxylate

생성물 1

HCID 12474700HCID 12474700, 화합물수율 81.5%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

Ethyl 2-octylcycloprop-2-ene-1-carboxylate (1.12 g, 5 mmol) and 100 ml of 0.2 N potassium hydroxide were stirred at room temperature for one week. Ether was added and the phases were separated. The aqueous phase was acidified and extracted with methylene chloride. The organic phase was dried over magnesium sulfate and stripped to give 0.8 g of 2-octylcycloprop-2-ene-1-carboxylic acid.

후처리

  1. customthe phases were separated
  2. extractionextracted with methylene chloride
  3. dry with materialThe organic phase was dried over magnesium sulfate

출처 및 근거

ORD 기록
ord-cf19c3b1ee5b4fdeb74266067d37b03a
출처 데이터셋
uspto-grants-2002_04
특허 번호
US06365549B2

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