Oxalyl chloride → 2-Octylcycloprop-2-ene-1-carbonyl chloride

HRID 840085노트

반응식

HRID 840085 반응식
[CH2:1]([C:9]1[CH:10]([C:12]([OH:14])=O)[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C(Cl)(=O)C([Cl:18])=O>CCOCC>[CH2:1]([C:9]1[CH:10]([C:12]([Cl:18])=[O:14])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

참가 물질

4

반응물 2

HCID 65578Oxalyl chlorideHCID 12474700HCID 12474700, 화합물

생성물 1

HCID 226216452-Octylcycloprop-2-ene-1-carbonyl chloride수율 85.4%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

A solution of 2-octylcycloprop-2-ene-1-carboxylic acid (350 mg, 1.8 mmol) in ether was treated with 0.45 g (3.5 mmol) of oxalyl chloride at room temperature. The reaction mixture was stirred for one hour then stripped to give 330 mg of 2-octylcycloprop-2-ene-1-carbonyl chloride.

출처 및 근거

ORD 기록
ord-3e917755f873453e9da0451521c08301
출처 데이터셋
uspto-grants-2002_04
특허 번호
US06365549B2

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