Allyl bromide → HCID 20566762, 화합물
반응식
[CH2:1]([NH:5][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:8])=[O:7])[CH2:2][CH2:3][CH3:4].C(=O)([O-])[O-].[K+].[K+].[CH2:19](Br)[CH:20]=[CH2:21]>CO>[CH2:21]([N:5]([CH2:1][CH2:2][CH2:3][CH3:4])[S:6]([C:9]([F:12])([F:10])[F:11])(=[O:7])=[O:8])[CH:20]=[CH2:19]참가 물질
5
실험 절차
A mixture of N-butyltrifluoromethanesulfonamide (62.0 g, 0.302 mole), potassium carbonate (45.54 g, 0.330 mole) and methanol (250 ml) was refluxed with stirring for two hours. Allyl bromide (39.93 g, 0.330 mole) was then added and this mixture stirred under reflux for 24 hours, cooled, filtered, and the solvent evaporated in vacuo. The residue was fractionally distilled yielding 37.0 g (b.p. of 53°-58° C. at 0.07 torr) of the desired compound, N-allyl-N-butyltrifluoromethanesulfonamide.
후처리
- temperaturewas refluxed
- stirringthis mixture stirred
- temperatureunder reflux for 24 hours
- temperaturecooled
- filtrationfiltered
- customthe solvent evaporated in vacuo
- distillationThe residue was fractionally distilled
출처 및 근거
- ORD 기록
- ord-a47dfcdbc77f4442a03410e327d1f0ff
- 출처 데이터셋
- uspto-grants-1981_10
- 특허 번호
- US04293441
반응 노트
불러오는 중…