Methanol → HCID 20566262, 화합물

HRID 848065노트

반응식

HRID 848065 반응식
C1(C)C=C(C)C=C(C)C=1S(O)(=O)=[O:10].[C:14]1([S:20]([C:22]2[S:23][CH:24]=[CH:25][CH:26]=2)=[NH:21])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.CO.I([O-])(=O)(=O)=O.[Na+]>O>[C:14]1([S:20]([C:22]2[S:23][CH:24]=[CH:25][CH:26]=2)(=[NH:21])=[O:10])[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

참가 물질

5

반응물 3

HCID 887MethanolHCID 23667635Sodium periodateHCID 88772777HCID 88772777, 화합물

생성물 1

HCID 20566262HCID 20566262, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

10 g. Phenyl-(2-thienyl)-sulphimide mesitylene-sulphonate are dissolved in 200 ml. methanol. A solution of 7 g. sodium periodate in 150 ml. water are added dropwise thereto, whereafter the reaction mixture is stirred for 24 hours at ambient temperature. The reaction mixture is then rendered alkaline and evaporated on a rotary evaporator. The residue obtained is partitioned between water and dichloromethane and the organic phase is evaporated. There are obtained 3.7 g. phenyl-(2-thienyl)-sulphoximide which, after recrystallisation from ethyl acetate/isopropanol, melts at 133° C.

후처리

  1. customevaporated on a rotary evaporator
  2. customThe residue obtained
  3. customis partitioned between water and dichloromethane
  4. customthe organic phase is evaporated
  5. customThere are obtained 3.7 g
  6. customphenyl-(2-thienyl)-sulphoximide which, after recrystallisation from ethyl acetate/isopropanol, melts at 133° C.

출처 및 근거

ORD 기록
ord-f81957d4d822446ea1b6ad6d4afd2384
출처 데이터셋
uspto-grants-1981_10
특허 번호
US04294838

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