4-Pentenoic acid → 1-Cyclohexyl-10,10-dimethyl-1,11-diaminoundecane

HRID 848811노트

반응식

HRID 848811 반응식
[C:1]1([CH:7]([NH2:21])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([CH3:20])([CH3:19])[CH2:17][NH2:18])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C=CCCC(O)=O>[Ru].C>[CH:1]1([CH:7]([NH2:21])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([CH3:19])([CH3:20])[CH2:17][NH2:18])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

참가 물질

4

반응물 2

HCID 611384-Pentenoic acidHCID 204361271-Phenyl-10,10-dimethyl-1,11-diaminoundecane

생성물 1

HCID 204361331-Cyclohexyl-10,10-dimethyl-1,11-diaminoundecane

시약·촉매·용매 1

HCID 16218582Ruthenium carbon촉매

실험 절차

Hydrogenation of 1-phenyl-10,10-dimethyl-1,11-diaminoundecane in the presence of a ruthenium/charcoal catalyst; b.p. 147° C./4 Pa; nD20 =1.4805.

출처 및 근거

ORD 기록
ord-183f05dde9cb4ab89ce96bae54de3c2e
출처 데이터셋
uspto-grants-1981_10
특허 번호
US04297480

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