Isopropyl chloroformate → Phosphinecarboxylic acid, dimethoxy-, 1-methylethyl ester, oxide

HRID 851706노트

반응식

HRID 851706 반응식
C[O:2][P:3]([O:6][CH3:7])[O:4][CH3:5].Cl[C:9]([O:11][CH:12]([CH3:14])[CH3:13])=[O:10]>>[CH:12]([O:11][C:9]([P:3](=[O:2])([O:6][CH3:7])[O:4][CH3:5])=[O:10])([CH3:14])[CH3:13]

참가 물질

3

반응물 2

HCID 7917Isopropyl chloroformateHCID 8472Trimethyl phosphite

생성물 1

HCID 512107Phosphinecarboxylic acid, dimethoxy-, 1-methylethyl ester, oxide

실험 절차

From 10.0 ml (85 mmole) of trimethylphosphite and 7.8 g (64 mmole) of i-propyl chloroformate. (100° C., 2 hours). Yield 8.0 g (64%). Bp2 90°-2° C. nD25 1,4202.

후처리

  1. custom(100° C., 2 hours)
  2. customBp2 90°-2° C.

출처 및 근거

ORD 기록
ord-9f7924b51e93442ebea3ff9b2f82267e
출처 데이터셋
uspto-grants-1983_05
특허 번호
US04386081

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