Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Quinoline → 5-Decenoic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Quinoline | HCID 7047 | — |
| 반응물 | Methyl 6-bromodecanoate | HCID 22931398 | — |
| 반응물 | Dec-6-enoic acid | HCID 53401195 | — |
| 반응물 | Methyl 6-decenoate | HCID 53854285 | — |
| 반응물 | Methyl 5-decenoate | HCID 54534253 | — |
| 생성물 | 5-Decenoic acid | HCID 53400879 | 35% |
반응 단계
Methyl 6-bromodecanoate (1.2 g) and quinoline (1.2g) were mixed together, and then allowed to react at 240° C. for 5 minutes. After the reaction was completed, the reaction solution was extracted with ether, washed with dilute sulfuric acid, washed with water, dried, evaporated to remove the solvent, and then distilled, thereby giving a mixture of methyl 5-decenoate and methyl 6-decenoate (310 mg). The mixture was hydrolyzed in a coventional manner, thereby giving a mixture (270 mg) of 5-decenoic acid and 6-decenoic acid (1/1).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07252849B2 |
| 출처 데이터셋 | uspto-grants-2007_08 |
| ORD ID | ord-8dd77bdcdc434d79a2d242b7afbf50d2 |
| 출처 메모 | uspto-grants-2007_08 |