Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cyclohexanol → HCID 58612895, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cyclohexanol | HCID 7966 | — |
| 반응물 | 1,2,3-Propanetricarboxylic acid | HCID 14925 | — |
| 촉매 | p-Toluenesulfonic acid | HCID 6101 | — |
| 용매 | Toluene | HCID 1140 | — |
| 용매 | Heptane | HCID 8900 | — |
| 생성물 | HCID 58612895 | HCID 58612895 | 83.4% |
반응 단계
A mixture of 1,2,3-propanetricarboxylic acid (25 g), cyclohexanol (55 g), and p-toluenesulfonic acid (100 mg) in toluene (500 mL) was refluxed for 2 days and water removed from the reaction mixture. After reaction was complete, solvent was removed in vacuuo to yield a viscous oil. The crude material was redissolved in heptane and passed through a pad of silica gel to obtain 1,2,3-propanetricarboxylic acid tricyclohexyl ester (50 g) as a pale yellow oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07252865B2 |
| 출처 데이터셋 | uspto-grants-2007_08 |
| ORD ID | ord-7e233837b41f4ef9a3784255f4e715dd |
| 출처 메모 | uspto-grants-2007_08 |