Methane → 4-Tetradecylbenzenediazonium nitrate

HRID 861182노트

반응식

HRID 861182 반응식
C.C1C(Br)=C(Br)[NH:4]C=1C(O)=O.N([O-])=O.[Na+].[CH2:16]([C:30]1[CH:36]=[CH:35][C:33]([NH2:34])=[CH:32][CH:31]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[N+:37]([O-:40])([OH:39])=[O:38]>O.CC(C)=O>[N+:37]([O-:40])([O-:39])=[O:38].[CH2:16]([C:30]1[CH:31]=[CH:32][C:33]([N+:34]#[N:4])=[CH:35][CH:36]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]

참가 물질

8

반응물 5

HCID 297Methane2회HCID 944Nitric AcidHCID 145224p-TetradecylanilineHCID 1618304,5-Dibromo-2-Pyrrolic AcidHCID 23668193Sodium Nitrite

생성물 1

HCID 197024474-Tetradecylbenzenediazonium nitrate

시약·촉매·용매 2

HCID 180Acetone용매HCID 962Water용매3회

실험 절차

A carbon black with a surface area of 58 m2 /g and a DBPA of 46 ml/100 g was used. A suspension of 50 g of this carbon black was prepared by stirring it into 450 g of water. A solution of 0.85 g of NaNO2 in 4 g of cold water was slowly added to a dispersion of 2.98 g of 4-tetradecylaniline, 1.98 g of concentrated nitric acid and 4 ml of acetone in 15 g of water that was cooled in an ice bath. 4-Tetradecylbenzenediazonium nitrate was formed. After 15 minutes of stirring, the mixture was added to the stirring carbon black suspension. Bubbles were released. After 30 minutes, the product was collected by filtration, washed with water and tetrahydrofuran (THF) and dried in an oven at 125° C. The carbon black product had attached p-C6 H4C14H29 groups.

후처리

  1. customwas prepared
  2. temperaturewas cooled in an ice bath

출처 및 근거

ORD 기록
ord-f7cbdd8d4b9c46aa8b4db7a1f2400d52
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05713988

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