Methane → Benzenediazonium, nitrate (1:1)

HRID 861183

반응식

HRID 861183 반응식
C.C1C(Br)=C(Br)[NH:4]C=1C(O)=O.N([O-])=O.[Na+].[NH2:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1.[N+:23]([O-:26])([OH:25])=[O:24]>C(O)(C)C.O>[N+:23]([O-:26])([O-:25])=[O:24].[C:17]1([N+:16]#[N:4])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

참가 물질

8

반응물 5

HCID 297Methane2회HCID 944Nitric AcidHCID 6115AnilineHCID 1618304,5-Dibromo-2-Pyrrolic AcidHCID 23668193Sodium Nitrite

생성물 1

HCID 61161Benzenediazonium, nitrate (1:1)

시약·촉매·용매 2

HCID 3776Isopropanol촉매HCID 962Water용매3회

실험 절차

A carbon black with a CTAB surface area of 350 m2 /g and a DBPA of 120 ml/100 g was used. A suspension of 50 g of this carbon black was prepared by stirring it into 450 g of water that contained a few drops of isopropanol. A solution of 5.12 g of NaNO2 in 10 g of cold water was slowly added to a solution of 5.62 g of aniline and 11.88 g of concentrated nitric acid in 10 g of water that was cooled in an ice bath. Benzenediazonium nitrate was formed. After 15 minutes of stirring, the mixture was added to the stirring carbon black suspension. Bubbles were released. When the bubbling had stopped, the product was collected by filtration, washed twice with water and dried in an oven at 125° C. The carbon black product had attached phenyl groups.

후처리

  1. customwas prepared
  2. temperaturewas cooled in an ice bath

출처 및 근거

ORD 기록
ord-e5450e9857384a10bea6844106c7285e
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05713988

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