Sodium Nitrate → HCID 22097084, 화합물

HRID 861450노트

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HRID 861450 반응식
[C:1]([NH:4][C:5]1[CH:6]=[C:7]([Cl:15])[CH:8]=[CH:9][C:10]=1[NH:11][C:12](=[O:14])[CH3:13])(=[O:3])[CH3:2].[N+:16]([O-])([O-:18])=[O:17].[Na+]>S(=O)(=O)(O)O>[C:12]([NH:11][C:10]1[C:5]([NH:4][C:1](=[O:3])[CH3:2])=[CH:6][C:7]([Cl:15])=[C:8]([N+:16]([O-:18])=[O:17])[CH:9]=1)(=[O:14])[CH3:13]

참가 물질

4

반응물 2

HCID 24268Sodium NitrateHCID 221796N-(2-acetamido-4-chlorophenyl)acetamide

생성물 1

HCID 22097084HCID 22097084, 화합물수율 63%

시약·촉매·용매 1

HCID 1118Sulfuric Acid용매

실험 절차

A solution of 5 g (22 mmol) of 3,4-diacetamido-1-chlorobenzene in 50 ml of concentrated sulfuric acid was cooled to 0° C., and 1.9 g (8.5 mmol) of sodium nitrate were added a little at a time, and the mixture was stirred at room temperature for 15 minutes. It was then poured into ice-water, and the crude product was filtered off with suction and washed with water. A yield of 63% of the product was obtained. Melting point 232° C.

후처리

  1. filtrationthe crude product was filtered off with suction
  2. washwashed with water

출처 및 근거

ORD 기록
ord-fbf9a0bace9842a881c3d52d1cf98966
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05714489

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