Sulfuric Acid → (1,3-Phenylenebis(1-methylethylidene))bis(tert-butyl) peroxide

HRID 862374

반응식

HRID 862374 반응식
[C:1]([O:5][OH:6])([CH3:4])([CH3:3])[CH3:2].O[C:8]([C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([C:17]([OH:20])([CH3:19])[CH3:18])[CH:12]=1)([CH3:10])[CH3:9].S(=O)(=O)(O)O>>[C:1]([O:5][O:6][C:8]([C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([C:17]([O:20][O:5][C:1]([CH3:4])([CH3:3])[CH3:2])([CH3:19])[CH3:18])[CH:12]=1)([CH3:10])[CH3:9])([CH3:4])([CH3:3])[CH3:2]

참가 물질

4

반응물 3

HCID 1118Sulfuric AcidHCID 6410tert-Butyl hydroperoxideHCID 74816alpha,alpha'-Dihydroxy-1,3-diisopropylbenzene

생성물 1

HCID 16654(1,3-Phenylenebis(1-methylethylidene))bis(tert-butyl) peroxide

실험 절차

1,3-Bis(2-t-butylperoxy-2-propyl)benzene (meta I) was prepared by reacting 29.7 grams (0.231 mole) of aqueous 70% t-butyl hydroperoxide with 20.4 grams (0.105 mole) of 1,3-bis(2-hydroxy-2-propyl)benzene in the presence of 26.8 grams (0.21 mole) of 77% sulfuric acid according to the procedure of Example I. The stripped product weighed 32.6 grams. It crystallized upon cooling and had a melting point of 45°-52° C. This example is for comparative purposes and does not fall under the specifications of this invention. The peroxide assay was 97% of theoretical.

후처리

  1. customIt crystallized
  2. temperatureupon cooling

출처 및 근거

ORD 기록
ord-0c0cf85aee744ec5959219b79a0710f7
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05719096

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