1,3-Cyclopentadiene, 5-(1-methylethylidene)- → Lithium tert-butylcyclopentadienide

HRID 863390노트

반응식

HRID 863390 반응식
[CH3:1][C:2]([CH3:8])=[C:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1.[CH3:9][Li:10]>C(OCC)C>[C:2]([C-:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1)([CH3:9])([CH3:8])[CH3:1].[Li+:10]

참가 물질

4

반응물 2

HCID 1374671,3-Cyclopentadiene, 5-(1-methylethylidene)-HCID 178418348HCID 178418348, 화합물

생성물 1

HCID 12713396Lithium tert-butylcyclopentadienide

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

To a solution of 4.18 g (39.4 mmol) 6,6-dimethylfulvene in 80 mL diethylether at 0° C. were added 22.9 mL of a 1.72M (39.4 mmol) methyl lithium solution in ether. The resulting slurry was stirred several days, then filtered, washed with pentane and dried under vacuum.

후처리

  1. filtrationfiltered
  2. washwashed with pentane
  3. customdried under vacuum

출처 및 근거

ORD 기록
ord-019418057763452d91d933b124ed72ee
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05721185

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