Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
tert-Butyl hydroperoxide → HCID 19050660, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | tert-Butyl hydroperoxide | HCID 6410 | — |
| 반응물 | HCID 19050670 | HCID 19050670 | — |
| 촉매 | Dicobalt Octacarbonyl (stabilized with 1-5% Hexane) | HCID 25049 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | HCID 19050660 | HCID 19050660 | — |
반응 단계
A solution of 100 mg of N-methyl 3-phenyl-5-(4,6-dimethoxy-2-pyrimidinylmethyl)-4-isoxazolecarboxanilide, 20 mg of dicobalt octacarbonyl, and 1 ml of t-butylhydroperoxide, in 60 ml of acetonitrile is refluxed for 48 hours. An additional 1 ml of t-butylhydroperoxide is added after 12 hrs and 24 hrs. Thin layer chromatography after 48 hrs indicates the presence of starting material and the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05561101 |
| 출처 데이터셋 | uspto-grants-1996_10 |
| ORD ID | ord-776e651b363d4802847ce5c4cfead691 |
| 출처 메모 | uspto-grants-1996_10 |