Dichloro-N,N-diethylmethaniminium chloride → HCID 178463872, 화합물

HRID 866269노트

반응식

HRID 866269 반응식
[NH2:1][C:2]1[CH:3]=[C:4]([C:9]2[CH:16]=[CH:15][CH:14]=[CH:13][C:10]=2[C:11]#[N:12])[CH:5]=[CH:6][C:7]=1[NH2:8].[Cl-].Cl[C:19](=[N+:21]([CH2:24][CH3:25])[CH2:22][CH3:23])Cl>>[C:11]([C:10]1[CH:13]=[CH:14][CH:15]=[CH:16][C:9]=1[C:4]1[CH:5]=[CH:6][C:7]2[NH:8][C:19]([N:21]([CH2:24][CH3:25])[CH2:22][CH3:23])=[N:1][C:2]=2[CH:3]=1)#[N:12]

참가 물질

3

반응물 2

HCID 12331502Dichloro-N,N-diethylmethaniminium chlorideHCID 21468845HCID 21468845, 화합물

생성물 1

HCID 178463872HCID 178463872, 화합물

실험 절차

2-(3,4-Diaminophenyl)benzonitrile (4.78 mmoles, 1.0 g) was reacted as described in Example 31 with (dichloromethylene) diethylammonium chloride (1.435 mmoles, 2.73 g prepared following the procedure described in Angew. Chem. Int. Ed. 12: 806 (1973)) to yield 0.91 g of 5-(2-cyanophenyl)-2-diethylamino-1H-benzimidazole.

후처리

  1. customprepared

출처 및 근거

ORD 기록
ord-7633100d0e8245da8b70c80f1adabe53
출처 데이터셋
uspto-grants-1996_10
특허 번호
US05569768

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