Water → Bisphenol E

HRID 866722

반응식

HRID 866722 반응식
C(C1C=[C:7]([CH2:16][CH2:17][C:18]2[CH:23]=[C:22](C(C)(C)C)[C:21]([OH:28])=[C:20](C(C)(C)C)[CH:19]=2)[CH:8]=[C:9]([C:12]([CH3:15])(C)C)C=1O)(C)(C)C.[CH2:33]1C2C(=CC=CC=2)CCC1.[OH2:43]>C1(C)C=CC(S(O)(=O)=O)=CC=1>[CH3:33][CH:17]([C:18]1[CH:19]=[CH:20][C:21]([OH:28])=[CH:22][CH:23]=1)[C:16]1[CH:7]=[CH:8][C:9]([OH:43])=[CH:12][CH:15]=1

참가 물질

5

반응물 3

HCID 962WaterHCID 8404TetralinHCID 1648474,4'-(1,2-Ethanediyl)bis(2,6-bis(1,1-dimethylethyl)phenol

생성물 1

HCID 608116Bisphenol E수율 97%

시약·촉매·용매 1

HCID 6101p-Toluenesulfonic acid용매

실험 절차

A solution of 5.0 grams (0.011 mole) of 1,2-bis(3,5-di-t-butyl-4-hydroxyphenyl)ethane dissolved in 30 milliliters of tetralin containing 0.2 gram (0.0012 mole) of p-toluensulfonic acid was heated to reflux for a total of 3 hours. The reaction mixture was cooled and poured into 50 milliliters of water. The precipitated solid was collected by suction filtration and recrystallized from ethanol to yield 2.3 grams (97 percent) of bisphenol E, melting point 199°-200° C.

후처리

  1. temperaturewas heated
  2. temperatureto reflux for a total of 3 hours
  3. temperatureThe reaction mixture was cooled
  4. filtrationThe precipitated solid was collected by suction filtration
  5. customrecrystallized from ethanol

출처 및 근거

ORD 기록
ord-9f1db7b4ffdc4dc9b504e7f12c195db1
출처 데이터셋
uspto-grants-1978_07
특허 번호
US04101391

연결된 노트

불러오는 중…