Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl chloride → 1-(3,3-Dimethylcyclohexyl)ethanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 1-(3,3-Dimethylcyclohexyl)ethanone | HCID 91388 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 1-(3,3-Dimethylcyclohexyl)ethanone | HCID 91388 | — |
| 생성물 | 1-(3,3-Dimethylcyclohexyl)-pent-4-en-1-one | HCID 6453423 | — |
| 생성물 | 1-Acetyl-3,3-dimethyl-1-(2-pentenyl) cyclohexane | HCID 53724607 | — |
반응 단계
A mixture of 1-acetyl-3,3-dimethylcyclohexane (156 grams, 1 mole), sodium hydroxide (60 grams, 1.5 moles), allyl chloride (114 grams, 1.5 moles) and triethylamine (10 grams) is stirred and heated at 80°-84° C. for 12 hours. The reaction mass is cooled to room temperature. Water is added with stirring, and the aqueous layer is discarded. The organic layer is distilled to afford 119 grams of 1-acetyl-3,3-dimethylcyclohexane, 31 grams of 1-acetyl-3,3-dimethyl-1-(2-pentenyl) cyclohexane, and 5 grams of 3,3-dimethyl-1-(4-pentenoyl) cyclohexane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04102928 |
| 출처 데이터셋 | uspto-grants-1978_07 |
| ORD ID | ord-eea4779a8076450b860971bd9ec322b9 |
| 출처 메모 | uspto-grants-1978_07 |