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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 867853생성일: 2026년 10월 26일

3-Methylcatechol → 5-Hydroxyindole

https://huagongshe.com/reaction/867853

반응식

참여 물질

역할이름HCID투입량
반응물3-MethylcatecholHCID 340—
반응물DopamineHCID 681—
반응물3-MethoxycatecholHCID 13622—
반응물5-HydroxyindoleHCID 16054—
반응물1H-indol-4-olHCID 75421—
반응물3,6-Dimethylbenzene-1,2-diolHCID 11469114—
반응물Sodium periodateHCID 23667635—
생성물5-HydroxyindoleHCID 16054—
생성물1H-indol-4-olHCID 75421—
생성물6-HydroxyindoleHCID 524508—
생성물7-HydroxyindoleHCID 2737651—

반응 단계

Mixtures of 4-hydroxyindole (0.1-10%) and 5-hydroxyindole (0.1-10%), 6-hydroxyindole (0.1-10%), or 7-hydroxyindole (0.1-10%) will give a color range from black to light auburn. 5-Hydroxyindole (0.1-10%) was found to produce progressively darker browns and, eventually, black through the addition of 3-methylcatechol (0.1-10%), 3-methoxycatechol (0.1-10%), or 3,6-dimethylcatechol (0.1-10%) followed by oxidation by sodium periodate (15%). 4-Hydroxyindole (1%) was found to produce progressively lighter colors with increasing red highlights through the addition of dopamine (2-5%) when penetration of precursors was done at high pH (9.2). Therefore a range of colors from light brown to black can be obtained through combinations of 4-hydroxyindole, 5-hydroxyindole, 6-hydroxyindole, and 7-hydroxyindole with each other or various other dye precursors. Similar results were obtained in staining skin in that a range of shades from light to dark brown can be obtained through combinations of hydroxyindoles with various other dye precursors.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04776857
출처 데이터셋uspto-grants-1988_10
ORD IDord-479fcc00a3ac46219fa1ab4996bf34a8
출처 메모uspto-grants-1988_10