Isopropyl iodide → 9H-Fluorene, 9-(1-methylethyl)-

HRID 871192노트

반응식

HRID 871192 반응식
[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[Li][CH2:15][CH2:16][CH2:17]C.IC(C)C.OC1O[C@@H](CO)[C@H](O)[C@H](O)[C@H]1O>>[CH:16]([CH:12]1[C:11]2[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=2[C:5]2[C:13]1=[CH:1][CH:2]=[CH:3][CH:4]=2)([CH3:17])[CH3:15]

참가 물질

5

반응물 4

HCID 6362Isopropyl iodideHCID 6853FluoreneHCID 10219674L-AltroseHCID 178418339Butyllithium

생성물 1

HCID 186969H-Fluorene, 9-(1-methylethyl)-

실험 절차

Fluorene (15.0 g, 90.4 mmol), n-BuLi (48.1 ml, 120 mmol, 2.5 M in hexane), RX=2-iodopropane (14.0 ml, 139.6 mmol). 42 was isolated as a yellowish solid (18.7 g, quant.). The analytical data were identical with these to be found in the literature (M. A. Schmidt, H. G. Alt, W. Milius, J. Organomet. Chem. 1996, 525, 15).

후처리

  1. custom42 was isolated as a yellowish solid (18.7 g, quant.)

출처 및 근거

ORD 기록
ord-1e83d68f28a54b908502277d24e24173
출처 데이터셋
uspto-grants-2015_03
특허 번호
US08969624B2

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