Peracetic Acid → (6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol

HRID 872426

반응식

HRID 872426 반응식
[CH3:1][C:2]1[CH2:7][CH2:6][CH:5]([CH2:8][OH:9])[CH2:4][CH:3]=1.C(OO)(=[O:12])C>C(OCC)(=O)C>[CH3:1][C:2]12[O:12][CH:7]1[CH2:6][CH:5]([CH2:8][OH:9])[CH2:4][CH2:3]2

참가 물질

4

반응물 2

HCID 6585Peracetic AcidHCID 5646723-Cyclohexene-1-methanol, 4-methyl-

생성물 1

HCID 86623394(6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol수율 95%

시약·촉매·용매 1

HCID 8857Ethyl Acetate용매

실험 절차

Epoxidation of 12.6 g (0.1 mol) of (4-methylcyclohex-3-enyl)methanol was performed with a 5 percent by weight solution of peroxyacetic acid in ethyl acetate at 65° C. The epoxidized product was purified by distillation and thereby yielded 12 g of (6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol with a purity of 98%.

후처리

  1. distillationThe epoxidized product was purified by distillation

출처 및 근거

ORD 기록
ord-31a9f14e942a47a2a60663b414812bce
출처 데이터셋
uspto-grants-2015_03
특허 번호
US08975349B2

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