Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Butene → Cis-11-tetradecenol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Butene | HCID 7844 | — |
| 반응물 | 9-Dodecen-1-ol, (9Z)- | HCID 6431342 | — |
| 반응물 | 11-Eicosenol | HCID 44134689 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Cis-11-tetradecenol | HCID 1712010 | 47% |
반응 단계
According to the procedure for compound 7, 11-eicosenol (1.1 g, 3.7 mmol) and THF (3 mL) were reacted with 1 (0.047 g, 2 mol %) and 1-butene to provide 9 (0.37 g, 47% yield, 76% Z as determined by 13C-NMR) as a colorless oil; 1H NMR (CDCl3): δ 5.29-5.45 (2H, m), 3.63 (2H, t, J=6.6 Hz), 1.94-2.06 (4H, m), 1.56 (2H, dt, J=13.5, 6.7 Hz), 1.27, (15H, m), 0.96 (3H, m); 13C NMR (CDCl3): δ 131.7, 129.5, 63.2, 33.0, 29.9, 29.7, 29.7, 29.7, 29.6, 29.4, 27.2, 25.9, 20.7, 14.6; HRMS (FAB): 212.2135, [C14H28O]+ requires 212.2140.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08987531B2 |
| 출처 데이터셋 | uspto-grants-2015_03 |
| ORD ID | ord-e7233ce930e14a8389794ba01fe02f8d |
| 출처 메모 | uspto-grants-2015_03 |