1-Hexene → 8Z-Tridecenyl acetate

반응식

[CH2:1]=[CH:2][CH2:3][CH2:4]CC.[C:7]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH:18]=[CH2:19])(=[O:9])[CH3:8]>>[C:7]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17]/[CH:18]=[CH:19]\[CH2:1][CH2:2][CH2:3][CH3:4])(=[O:9])[CH3:8]

참가 물질

반응물 2

HCID 115971-Hexene

HCID 15673852Non-8-enyl acetate

생성물 1

HCID 100145388Z-Tridecenyl acetate

실험 절차

Reactions between 1-hexene and 8-nonenyl acetate were conducted using methods analogous to those described above using to form the pheromone derivative 17. When catalyzed by Ruthenium complex 1, the reaction proceeded in good yield (67%) with high Z-selectivity (91%) at a low catalyst loading (0.5 mol %).

후처리

customto form the pheromone derivative 17
customin good yield (67%) with high Z-selectivity (91%) at a low catalyst loading (0.5 mol %)

출처 및 근거

ORD 기록: ord-d311f3ee92db431b8a0eb371d8b2f2af
출처 데이터셋: uspto-grants-2015_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08987531B2

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