Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
N-bromobutanimide → 9-Bromo-10-phenanthren-3-ylanthracene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | N-bromobutanimide | HCID 67184 | — |
| 반응물 | 9-Phenanthren-3-ylanthracene | HCID 59629500 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 9-Bromo-10-phenanthren-3-ylanthracene | HCID 59629544 | 95% |
반응 단계
30 g (80 mmol) of 9-phenanthren-3-ylanthracene are suspended in 300 ml of THF, 14.2 g (80 mmol) of NBS are added, and the mixture is stirred at RT for 2 h with exclusion of light. The solvent is subsequently removed in vacuo, and the residue is boiled in EtOH and recrystallised twice from dioxane, leaving 32.9 g (95%) of bromide as yellow crystals.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08993123B2 |
| 출처 데이터셋 | uspto-grants-2015_03 |
| ORD ID | ord-ca49e2514dd84347be27c4257bab1c98 |
| 출처 메모 | uspto-grants-2015_03 |