Z-3-(1,3-dioxan-2-yl)-1-(2-pyridyl)-1-propene → 1-(1,3-Dioxan-2-yl)-3-(2-pyridyl)propane
반응식
[O:1]1[CH2:6][CH2:5][CH2:4][O:3][CH:2]1[CH2:7]/[CH:8]=[CH:9]\[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=1>[Pd]>[O:1]1[CH2:6][CH2:5][CH2:4][O:3][CH:2]1[CH2:7][CH2:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=1참가 물질
3
실험 절차
Through a suspension of 800 mg (4.2 mmol) of olefin 149 and 100 mg of 10% palladium on carbon was bubbled a steady stream of hydrogen gas for a period of 10 min. The reaction mixture was then filtered through celite and concentrated to give 805 mg of the acetal 150 as a colorless oil. 1H NMR consistent with structure.
후처리
- customwas bubbled a steady stream of hydrogen gas for a period of 10 min
- filtrationThe reaction mixture was then filtered through celite and
- concentrationconcentrated
출처 및 근거
- ORD 기록
- ord-600c0203d0174eabae949b47eb4ee810
- 출처 데이터셋
- uspto-grants-1998_03
- 특허 번호
- US05723459
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