Potassium Iodide → Methyl 2-acetylheptanoate

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[CH3:1][O:2][C:3](=[O:8])/[CH:4]=[C:5](/[O-:7])\[CH3:6].[Na+].[I-].[K+].[CH2:12](Br)[CH2:13][CH2:14][CH2:15][CH3:16]>>[C:5]([CH:4]([CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[C:3]([O:2][CH3:1])=[O:8])(=[O:7])[CH3:6]

참가 물질

반응물 3

HCID 4875Potassium Iodide

HCID 80571-Bromopentane

HCID 23681258sodium (2E)-4-methoxy4-oxo-2-buten-2-olate

생성물 1

HCID 10511765Methyl 2-acetylheptanoate

실험 절차

Analogously to Example 14A, 30 g (217 mmol) of sodium (2E)-4-methoxy-4-oxo-2-buten-2-olate (Example 13A) and 1.24 g (7.5 mmol) of potassium iodide are reacted with 32.8 g (217 mmol) of n-pentyl bromide to give methyl 2-acetylheptanoate.

출처 및 근거

ORD 기록: ord-3218440b62ef4668817da9c97c355450
출처 데이터셋: uspto-grants-2006_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06998402B2

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