Potassium Iodide → Methyl 2-acetyloctanoate

HRID 890700

반응식

HRID 890700 반응식
[CH3:1][O:2][C:3](=[O:8])/[CH:4]=[C:5](/[O-:7])\[CH3:6].[Na+].[I-].[K+].[CH2:12](Br)[CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]>>[C:5]([CH:4]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[C:3]([O:2][CH3:1])=[O:8])(=[O:7])[CH3:6]

참가 물질

4

반응물 3

HCID 4875Potassium IodideHCID 81011-BromohexaneHCID 23681258sodium (2E)-4-methoxy4-oxo-2-buten-2-olate

생성물 1

HCID 3390996Methyl 2-acetyloctanoate

실험 절차

Analogously to Example 14A, 30 g (217 mmol) of sodium (2E)-4-methoxy-4-oxo-2-buten-2-olate (Example 13A) and 1.24 g (7.5 mmol) of potassium iodide are reacted with 37.7 g (228 mmol) of hexyl bromide to give methyl 2-acetyloctanoate.

출처 및 근거

ORD 기록
ord-595fc6a914d64e1fbf8e10003148cc40
출처 데이터셋
uspto-grants-2006_02
특허 번호
US06998402B2

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