참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Cyclohexane | HCID 8078 | — |
| 반응물 | 4-dodecyloxycarbonyl-N-hydroxyphthalimide | HCID 10915765 | — |
| 반응물 | Nitrogen Dioxide | HCID 178526396 | — |
| 촉매 | Manganous Acetate | HCID 12525 | — |
| 생성물 | Adipic Acid | HCID 196 | — |
| 생성물 | Glutaric Acid | HCID 743 | — |
| 생성물 | Cyclohexanol | HCID 7966 | — |
| 생성물 | Cyclohexanone | HCID 7967 | — |
반응 단계
A mixture of 4 ml (37 mmol) of cyclohexane, 0.1 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide, 0.01 mmol of acetylacetonatocobalt(II), 0.001 mmol of manganese(II) acetate and 0.06 mmol of nitrogen dioxide was stirred at 80° C. in an atmosphere of air (10 atm=1 MPa) for 2 hours and thereby yielded 0.30 mmol of cyclohexyl alcohol, 0.65 mmol of cyclohexanone, 0.10 mmol of adipic acid and 0.09 mmol of glutaric acid. The total amount of the four products was 1.14 mmol, and the amount of K/A oil was 0.95 mmol.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06998491B2 |
|---|
| 출처 데이터셋 | uspto-grants-2006_02 |
|---|
| ORD ID | ord-088c231e604341168519ced288e0b34e |
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| 출처 메모 | uspto-grants-2006_02 |
|---|
