Cyclohexane → Adipic Acid

HRID 890843

반응식

HRID 890843 반응식
[CH2:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O:19][C:20]([C:22]1[CH:23]=[C:24]2[C:29](=[O:30])N(O)[C:26](=[O:27])[C:25]2=[CH:32][CH:33]=1)=[O:21])CCCCCCCCCCC.[N+]([O-])=[O:35]>C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[CH:1]1([OH:19])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:22]1(=[O:35])[CH2:23][CH2:24][CH2:25][CH2:32][CH2:33]1.[C:20]([OH:19])(=[O:21])[CH2:22][CH2:23][CH2:24][CH2:25][C:26]([OH:27])=[O:35].[C:20]([OH:19])(=[O:21])[CH2:22][CH2:23][CH2:24][C:29]([OH:30])=[O:35]

참가 물질

8

반응물 3

HCID 8078CyclohexaneHCID 109157654-dodecyloxycarbonyl-N-hydroxyphthalimideHCID 178526396Nitrogen Dioxide

생성물 4

HCID 196Adipic AcidHCID 743Glutaric AcidHCID 7966CyclohexanolHCID 7967Cyclohexanone

시약·촉매·용매 1

HCID 12525Manganous Acetate촉매

반응 조건

온도
80 °C

실험 절차

A mixture of 4 ml (37 mmol) of cyclohexane, 0.1 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide, 0.01 mmol of acetylacetonatocobalt(II), 0.001 mmol of manganese(II) acetate and 0.06 mmol of nitrogen dioxide was stirred at 80° C. in an atmosphere of air (10 atm=1 MPa) for 2 hours and thereby yielded 0.30 mmol of cyclohexyl alcohol, 0.65 mmol of cyclohexanone, 0.10 mmol of adipic acid and 0.09 mmol of glutaric acid. The total amount of the four products was 1.14 mmol, and the amount of K/A oil was 0.95 mmol.

출처 및 근거

ORD 기록
ord-088c231e604341168519ced288e0b34e
출처 데이터셋
uspto-grants-2006_02
특허 번호
US06998491B2

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