Isobutylene → N-phenylmaleimide isobutene

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In a one-liter autoclave were charged 400 ml of toluene as a polymerization solvent, 0.001 moles of perbutyl neodecanoate as a polymerization initiator, 0.42 moles of N-phenylmaleimide, and 4.05 moles of isobutene, and the mixture was subjected to polymerization reaction under a polymerization condition at a polymerization temperature of 60° C. for a polymerization time of 5 hours, to obtain N-phenylmaleimide-isobutene alternating copolymer. The thus obtained N-phenylmaleimide-isobutene alternating copolymer had a weight average molecular weight (Mw) (as reduced into standard polystyrene) of 162,000 and an Mw/Mn of 2.6.

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