Trifluoroiodomethane → HCID 86743769, 화합물

HRID 893257노트

반응식

I[As:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[F:15][C:16]([F:19])([F:18])I>>[C:3]1([As:2]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:16]([F:19])([F:18])[F:15])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

반응물 2

HCID 16843Trifluoroiodomethane

HCID 238215Diphenylarsinous iodide

생성물 1

HCID 86743769HCID 86743769, 화합물

실험 절차

R. Cullen in an article "Perfluoroalkyl Arsenicals, Part II The Preparation and Properties of Aryl Perfluoroalkyl Arsenicals", reported in Canadian Journal of Chemistry, Volume 38, 1960, pg. 445-451, describes the reaction of iododiphenylarsine with trifluoroiodomethane to produce diphenyltrifluoromethylarsine. Thermal decomposition of diphenyltrifluoromethylarsine resulted in undisclosed black solid deposit.

출처 및 근거

ORD 기록: ord-9673e52b583a4cb3860e0a609d18591e
출처 데이터셋: uspto-grants-1992_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05124278

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