Phosphonium, hexyltriphenyl-, bromide (1:1) → 1-Benzyloxy-3-(1,1-dimethyloct-2-enyl)benzene

HRID 894422

반응식

HRID 894422 반응식
[CH2:1]([O:8][C:9]1[CH:10]=[C:11]([C:15]([CH3:19])([CH3:18])[CH:16]=O)[CH:12]=[CH:13][CH:14]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Br-].[CH2:21]([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)[CH2:22][CH2:23][CH2:24][CH2:25][CH3:26]>>[CH2:1]([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([C:15]([CH3:19])([CH3:18])[CH:16]=[CH:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

3

반응물 2

HCID 2724569Phosphonium, hexyltriphenyl-, bromide (1:1)HCID 198553592-(3-(Benzyloxy)phenyl)-2-methylpropanal

생성물 1

HCID 542462321-Benzyloxy-3-(1,1-dimethyloct-2-enyl)benzene수율 70%

실험 절차

Similarly, 1-benzyloxy-3-(1,1-dimethyloct-2-enyl)benzene (13.5 g., 70%) is prepared from 15.75 g. (0.062 mol.) of 2-(3-benzyloxyphenyl)-2-methylpropionaldehyde and 37.5 g. (0.0899 mol.) of hexyltriphenylphosphonium bromide. The product is an oil.

출처 및 근거

ORD 기록
ord-b791190f6f854cfa8fccf60aa8f18fb6
출처 데이터셋
uspto-grants-1981_08
특허 번호
US04283569

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