참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Bis(4-hydroxyphenyl)methane | HCID 12111 | — |
| 반응물 | Butyl glycidyl ether | HCID 17049 | — |
| 촉매 | Benzyltrimethylammonium chloride | HCID 5963 | — |
| 생성물 | Bis(p-(3-butoxy-2-hydroxypropyloxy)phenyl)methane | HCID 20574263 | — |
반응 단계
Bis(p-hydroxyphenyl)methane (303 g; 1.5 moles), butyl glycidyl ether of epoxide content 7.45 equiv./kg (402.7 g; 6 equiv.), and benzyltrimethylammonium chloride (3 g) were stirred together and heated to 100° C., at which temperature an exothermic reaction commenced. The mixture was kept at 120° C. by moderate cooling and then, when the temperature of the mixture began to fall, heating was resumed, keeping the temperature at 120° C. for 1 hour and 150° C. for 4 hours. The mixture was cooled, and its epoxide content was found to be 0.1 equiv./kg, indicating that the reaction was virtually complete.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US04284574 |
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| 출처 데이터셋 | uspto-grants-1981_08 |
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| ORD ID | ord-7ca643d425bc45448341e50a01dee08e |
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| 출처 메모 | uspto-grants-1981_08 |
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