Cyclododecanone → 1-(Morpholino-propoxyimino)cyclododecane

반응식

[C:1]1(=O)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.Cl.Cl.[O:16]1[CH2:21][CH2:20][N:19]([CH2:22][CH2:23][CH2:24][O:25][NH2:26])[CH2:18][CH2:17]1.C(O)(=O)/C=C/C([O-])=O>>[O:16]1[CH2:17][CH2:18][N:19]([CH2:22][CH2:23][CH2:24][O:25][N:26]=[C:1]2[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]2)[CH2:20][CH2:21]1

참가 물질

반응물 3

HCID 13246Cyclododecanone

HCID 6183479Fumarate(1-)

HCID 21978813Morpholinopropoxyamine dihydrochloride

생성물 1

HCID 132058081-(Morpholino-propoxyimino)cyclododecane

실험 절차

Starting from 18.23 g. (0.1 moles) of cyclododecanone and 25.64 g. (0.11 moles) of morpholinopropoxyamine dihydrochloride the title compound is prepared as in Example 13. Yield: 28.4 g. (87%). Hydrogen fumarate, m.p.: 118°-120° C.

출처 및 근거

ORD 기록: ord-d5d8d935a6644b63bbb2c593dad522e7
출처 데이터셋: uspto-grants-1981_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04285942

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