Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethylamine → N'-hydroxynonanimidamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | Nonanenitrile | HCID 16715 | — |
| 반응물 | Hydroxyamine hydrochloride | HCID 443297 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | N'-hydroxynonanimidamide | HCID 5074022 | 27% |
반응 단계
Octyl cyanide (2 g, 14 mmol) and hydroxylamine hydrochloride (2.495 g, 36 mmol) were dissolved in EtOH (10 mL) and treated with triethylamine (5 mL, 36 mmol) at reflux over night. Extraction: AcOEt/water. Silica gel chromatography: heptane/AcOEt 1:2 afforded a white solid (0.65 g, 26%). MS: m/z=173 (M +H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07351700B2 |
| 출처 데이터셋 | uspto-grants-2008_04 |
| ORD ID | ord-344e2ede1a55402092f36b2c52f6ed11 |
| 출처 메모 | uspto-grants-2008_04 |