1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(4-hydroxybutyl)-N-methyl- → C4F9SO2N(CH3)(CH2)11OH

HRID 901315

반응식

HRID 901315 반응식
[C:1]([S:14]([N:17]([CH2:19]CCCO)[CH3:18])(=[O:16])=[O:15])([C:4]([C:7]([C:10]([F:13])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].C(S(NC)(=O)=O)(C(C(C(F)(F)F)(F)F)(F)F)(F)F.O(C)[Na].BrC[CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][OH:57]>COCCOCCOC>[C:1]([S:14]([N:17]([CH2:19][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][OH:57])[CH3:18])(=[O:16])=[O:15])([C:4]([C:7]([C:10]([F:11])([F:13])[F:12])([F:8])[F:9])([F:5])[F:6])([F:2])[F:3]

참가 물질

6

반응물 4

HCID 699391-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(4-hydroxybutyl)-N-methyl-HCID 7416311-Bromo-1-undecanolHCID 1099681,1,2,2,3,3,4,4,4-nonafluoro-N-methylbutane-1-sulfonamideHCID 178418582HCID 178418582, 화합물

생성물 1

HCID 131726834C4F9SO2N(CH3)(CH2)11OH

시약·촉매·용매 1

HCID 8150Diglyme용매

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온도
100 °C

실험 절차

C4F9SO2N(CH3)(CH2)11OH was prepared using a procedure similar to that described above for preparing C4F9SO2N(CH3)(CH2)4OH. 175.9 g C4F9SO2NHCH3 and 121.4 g 25% NaOCH3 were reacted to produce a solution of C4F9SO2NNaCH3 in about 100 mL diglyme. This solution was treated with 141 g 11-bromoundecanol (available from Aldrich) and heated at 100° C. for 20 hr to form a heavy precipitate. The reaction was quenched in about 600 mL warm water and the resulting lower layer was stripped at 50° C./0.5 mTorr to leave 269.9 g of C4F9SO2N(CH3)(CH2)11OH, a low-melting solid.

후처리

  1. customC4F9SO2N(CH3)(CH2)11OH was prepared
  2. customto form a heavy precipitate
  3. customThe reaction was quenched in about 600 mL
  4. temperaturewarm water
  5. customwas stripped at 50° C.

출처 및 근거

ORD 기록
ord-39c0e5cc0b934026948250077d6b552a
출처 데이터셋
uspto-grants-2008_04
특허 번호
US07361782B2

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