Hydrogen iodide → HCID 22138046, 화합물

HRID 901745노트

반응식

HRID 901745 반응식
[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4(O)[C:34]5[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=5[C:28]([C:36]5[CH:41]=[CH:40][CH:39]=[C:38]([C:42]6[C:43]7[C:48]([C:49]8[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=8[CH:55]=6)=[CH:47][CH:46]=[CH:45][CH:44]=7)[CH:37]=5)(O)[C:27]5[C:22]4=[CH:23][CH:24]=[CH:25][CH:26]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.I.[PH2](O)=O>C(O)(=O)C>[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4[C:22]5[C:27]([C:28]([C:36]6[CH:41]=[CH:40][CH:39]=[C:38]([C:42]7[C:43]8[C:48]([C:49]9[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=9[CH:55]=7)=[CH:47][CH:46]=[CH:45][CH:44]=8)[CH:37]=6)=[C:29]6[C:34]=4[CH:33]=[CH:32][CH:31]=[CH:30]6)=[CH:26][CH:25]=[CH:24][CH:23]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1

참가 물질

5

반응물 3

HCID 24841Hydrogen iodideHCID 4124402Phosphinic AcidHCID 22138029HCID 22138029, 화합물

생성물 1

HCID 22138046HCID 22138046, 화합물

시약·촉매·용매 1

HCID 176Acetic Acid용매

반응 조건

온도
100 °C

실험 절차

9,10-bis(3-(9-Phenanthryl)phenyl)-9,10-dihydroxy-9,10-dihydro-anthracene (5.2 g, 7.3 mmole) was suspended in acetic acid (120 ml). To the resultant suspension, a 57% hydroiodic acid (10 ml, 77 mmole, 10 eq) was added and the obtained mixture was stirred at 100° C. for 6 hours. To the reaction mixture, a 50% aqueous solution of hypophosphorous acid (40 ml) was added. The formed solid was separated by filtration and washed with water, methanol and acetone and a white solid (5.0 g, quant.) was obtained.

후처리

  1. customThe formed solid was separated by filtration
  2. washwashed with water, methanol and acetone
  3. customa white solid (5.0 g, quant.) was obtained

출처 및 근거

ORD 기록
ord-0eafd0390dc24f45934cc2b88df8a245
출처 데이터셋
uspto-grants-2008_04
특허 번호
US07361796B2

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