Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- → Tetracyanoquinodimethane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- | HCID 73696 | — |
| 촉매 | HCID 178418406 | HCID 178418406 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Tetracyanoquinodimethane | HCID 73697 | — |
반응 단계
According to the procedure of Fatiadi Synthesis, 1976, 133, incorporated herein by reference, the 1,4-bis(dicyanomethylene)cyclohexane is allowed to react with manganese dioxide in refluxing (110° C.) toluene for ca. 15 minutes to provide TCNQ in ca. 60% yields.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04229364 |
| 출처 데이터셋 | uspto-grants-1980_10 |
| ORD ID | ord-366e9c2a0e504e51b09d96e9e5139ab7 |
| 출처 메모 | uspto-grants-1980_10 |