Peracetic Acid → HCID 19010447, 화합물
반응식
[F:1][C:2]1[CH:3]=[C:4]([CH:12]=[CH:13][CH:14]=1)[O:5][C:6]1[CH:7]=[N:8][CH:9]=[CH:10][CH:11]=1.C(OO)(=[O:17])C>C(O)(=O)C>[F:1][C:2]1[CH:3]=[C:4]([CH:12]=[CH:13][CH:14]=1)[O:5][C:6]1[CH:7]=[N+:8]([O-:17])[CH:9]=[CH:10][CH:11]=1참가 물질
4
실험 절차
A solution of 32 g of 3-(3-fluorophenoxy)pyridine [Fr. Pat. No. 1,472,619 (1967)] in 50 ml of glacial acetic acid is treated with 35 g of 40% peracetic acid in acetic acid and the mixture is refluxed 16 hours. The mixture is concentrated at reduced pressure and the oil is dissolved in 250 ml of dichloromethane. The dichloromethane solution is washed with excess 10% sodium hydroxide solution. The solution is dried and concentrated to dryness to yield 3-(3-fluorophenoxy)pyridine 1-oxide, m.p. 63°-66° C.
후처리
- temperaturethe mixture is refluxed 16 hours
- concentrationThe mixture is concentrated at reduced pressure
- dissolutionthe oil is dissolved in 250 ml of dichloromethane
- washThe dichloromethane solution is washed with excess 10% sodium hydroxide solution
- customThe solution is dried
- concentrationconcentrated to dryness
출처 및 근거
- ORD 기록
- ord-83e20b08ca0448669fb98d659cc7192b
- 출처 데이터셋
- uspto-grants-1980_10
- 특허 번호
- US04229457
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